Hybrid Materials Based on Magnetic Layered Double Hydroxides: A Molecular Perspective

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• 作者：Gonzalo Abell谩n ; Carlos Mart铆-Gastaldo ; Antonio Ribera ; Eugenio Coronado
• 刊名：Accounts of Chemical Research
• 出版年：2015
• 出版时间：June 16, 2015
• 年：2015
• 卷：48
• 期：6
• 页码：1601-1611
• 全文大小：663K
• ISSN：1520-4898

文摘

Design of functional hybrids lies at the very core of synthetic chemistry as it has enabled the development of an unlimited number of solids displaying unprecedented or even improved properties built upon the association at the molecular level of quite disparate components by chemical design. Multifunctional hybrids are a particularly appealing case among hybrid organic/inorganic materials. Here, chemical knowledge is used to deploy molecular components bearing different functionalities within a single solid so that these properties can coexist or event interact leading to unprecedented phenomena. From a molecular perspective, this can be done either by controlled assembly of organic/inorganic molecular tectons into an extended architecture of hybrid nature or by intercalation of organic moieties within the empty channels or interlamellar space offered by inorganic solids with three-dimensional (MOFs, zeolites, and mesoporous hosts) or layered structures (phosphates, silicates, metal dichalcogenides, or anionic clays).