Absolute Configuration of Sporotricale and Structure of 6-Hydroxysporotricale
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文摘
The absolute configuration of the two stereocenters of (+)-sporotricale (2a), a bioactive phthalide secondary metabolite,was determined through circular dichroism and by applying Mosher's method. The structure of 6-hydroxysporotricale(2c), isolated from cultures in vitro of Sporotrichum laxum, was also elucidated.

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