Palladium-Catalyzed Regio- and Stereoselective Arylesterification of Ferrocenylallene: A Synthetic Route to Ferrocene-Containing Disubstituted E-Allylic Esters
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- 作者：Shufeng Chen ; Zhenlong Gao ; Haiying Zhao ; Baoguo Li
- 刊名：Journal of Organic Chemistry
- 出版年：2014
- 出版时间：February 7, 2014
- 年：2014
- 卷：79
- 期：3
- 页码：1481-1486
- 全文大小：325K
- ISSN：1520-6904
文摘
An efficient and concise protocol for the highly regio- and stereoselective synthesis of ferrocene-containing disubstituted E-allylic ester derivatives via a palladium-catalyzed intermolecular arylesterification reaction of ferrocenylallene with aryl iodides and carboxylic acids has been developed. The regio- and stereoselectivities of this reaction may be controlled by the steric effect of the bulky ferrocene group.