Contribution of Isoprene Epoxydiol to Urban Organic Aerosol: Evidence from Modeling and Measurements

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• 作者：Alexandra Karambelas ; Havala O. T. Pye ; Sri H. Budisulistiorini ; Jason D. Surratt ; Robert W. Pinder
• 刊名：Environmental Science & Technology Letters
• 出版年：2014
• 出版时间：June 10, 2014
• 年：2014
• 卷：1
• 期：6
• 页码：278-283
• 全文大小：332K
• 年卷期：v.1,no.6(June 10, 2014)

文摘

In a region heavily influenced by anthropogenic and biogenic atmospheric emissions, recent field measurements have attributed one-third of urban organic aerosol by mass to isoprene epoxydiols (IEPOX). These aerosols arise from the gas-phase oxidation of isoprene, the formation of IEPOX, the reactive uptake of IEPOX by particles, and finally the formation of new compounds in the aerosol phase. Using a continental-scale chemical transport model, we find a strong temporal correspondence between the simulated formation of IEPOX-derived organic aerosol and these measurements. However, because only a subset of isoprene-derived aerosol compounds have been specifically identified in laboratory studies, our simulation of known IEPOX-derived organic aerosol compounds predicts a mass 10-fold lower than the field measurements, despite abundant gas-phase IEPOX. Sensitivity studies suggest that increasing the effective IEPOX uptake coefficient and including aerosol-phase reactions that lead to the addition of functional groups could increase the simulated IEPOX-derived aerosol mass and account for the difference between the field measurements and modeling results.