Ferrimagnetic Ordering Due to Fe(III) d and Donor Spins in (Ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide)2&#
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- 作者：Takuya Matsumoto ; Toyonari Sugimoto ; Hiroko Aruga Katori ; Satoru Noguchi ; and Takekazu Ishida
- 刊名：Inorganic Chemistry
- 出版年：2004
- 出版时间：June 28, 2004
- 年：2004
- 卷：43
- 期：13
- 页码：3780 - 3782
- 全文大小：69K
- 年卷期：v.43,no.13(June 28, 2004)
- ISSN：1520-510X
文摘
Magnetization and heat capacity were measured down to 0.4 K ina 2:1 charge-transfer (CT) salt of a new donor molecule,ethylenedithiotetrathiafulvalenoquinone-1,3-dithiolemethide (1) witha magnetic FeBr4- ion (12·FeBr4). The Fe(III) d spins of FeBr4-ions were subject to apparently ferromagnetic interaction with eachother through the interaction with the 
spins developed bylocalization of the conducting electrons on the donor columns,eventually giving rise to ferrimagnetic ordering (FI) near 1 K, whichprovides the first example in a molecular -d system.
spins developed bylocalization of the conducting electrons on the donor columns,eventually giving rise to ferrimagnetic ordering (FI) near 1 K, whichprovides the first example in a molecular -d system.