Mechanism of Spontaneous Blebbing Motion of an Oil–Water Interface: Elastic Stress Generated by a Lamellar–Lamellar Transition

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• 作者：Yutaka Sumino ; Norifumi L. Yamada ; Michihiro Nagao ; Takuya Honda ; Hiroyuki Kitahata ; Yuri B. Melnichenko ; Hideki Seto
• 刊名：Langmuir
• 出版年：2016
• 出版时间：March 29, 2016
• 年：2016
• 卷：32
• 期：12
• 页码：2891-2899
• 全文大小：507K
• ISSN：1520-5827

文摘

A quaternary system composed of surfactant, cosurfactant, oil, and water showing spontaneous motion of the oil–water interface under far-from-equilibrium condition is studied in order to understand nanometer-scale structures and their roles in spontaneous motion. The interfacial motion is characterized by the repetitive extension and retraction of spherical protrusions at the interface, i.e, blebbing motion. During the blebbing motion, elastic aggregates are accumulated, which were characterized as surfactant lamellar structures with mean repeat distances d of 25 to 40 nm. Still unclear is the relationship between the structure formation and the dynamics of the interfacial motion. In the present study, we find that a new lamellar structure with d larger than 80 nm is formed at the blebbing oil–water interface, while the resultant elastic aggregates, which are the one reported before, have a lamellar structure with smaller d (25 to 40 nm). Such transition of lamellar structures from the larger d to smaller d is induced by a penetration of surfactants from an aqueous phase into the aggregates. We propose a model in which elastic stress generated by the transition drives the blebbing motion at the interface. The present results explain the link between nanometer-scale transition of lamellar structure and millimeter-scale dynamics at an oil–water interface.