Oxidation-Resistant Acidic Resins Prepared by Partial Carbonization as Cocatalysts in Synthesis of Adipic Acid

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• 作者：Huijuan Wei ; Hongbian Li ; Yangqing Liu ; Peng Jin ; Xiangyu Wang ; Baojun Li
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2012
• 出版时间：August 22, 2012
• 年：2012
• 卷：4
• 期：8
• 页码：4106-4112
• 全文大小：549K
• 年卷期：v.4,no.8(August 22, 2012)
• ISSN：1944-8252

文摘

The oxidation-resistant acidic resins are of great importance for the catalytic oxidation systems. In this paper, the oxidatively stable acidic resins are obtained from the cation ion exchange resins (CIERs) through the thermal treatment in N₂ atmosphere. The structure and properties of the thermally treated CIERs were characterized by chemical analysis, Fourier transform infrared (FT鈥揑R) spectra, acid capacity measurement and scanning electron microscope (SEM). The thermally treated CIERs possess high acid capacity up to 4.09 mmol g^鈥?. A partial carbonization is observed in the thermal treatment process of CIERs, but the morphology of resin spheres maintains well. The as-prepared CIERs are used as solid acids to assist the hydrogen peroxide oxidation of cyclohexene to adipic acid (ADA) with tungstic acid as the catalyst precursor. The improved yields of ADA in the recycling reaction are obtained in the presence of acidic CIERs. Meanwhile, the unproductive decomposition of H₂O₂ is effectively suppressed. The high yields of ADA (about 81%) are kept by the thermally treated CIERs even after the fifth cycle. The thermally treated CIERs exhibit excellent acid-catalytic performance and possess remarkable oxidation-resistant capability.

Keywords:

adipic acid; catalytic oxidation; oxidation-resistant resins; partial carbonization; thermal treatment