Multifunctional 3-Fold Interpenetrated Porous Metal鈥揙rganic Frameworks Composed of Unprecedented Self-Catenated Networks
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- 作者：Feng Luo ; Zi-Zun Yuan ; Xue-Feng Feng ; Stuart R. Batten ; Jian-Qiang Li ; Ming-Biao Luo ; Shu-Juan Liu ; Wen-Yuan Xu ; Gong-Ming Sun ; Yu-Mei Song ; Hai-Xiao Huang ; Xian-Zhao Tian
- 刊名：Crystal Growth & Design
- 出版年：2012
- 出版时间：July 3, 2012
- 年：2012
- 卷：12
- 期：7
- 页码：3392-3396
- 全文大小：338K
- 年卷期：v.12,no.7(July 3, 2012)
- ISSN：1528-7505
文摘
A 3-fold interpenetrating porous metal鈥搊rganic framework, namely, Zn(bdc)(L)路solvents (1, L = N4,N4鈥?di(pyridin-4-yl)biphenyl-4,4鈥?dicarboxamide, H2bdc = terephthalic acid), composed of self-catenated nets with unprecedented hxg-d-4-Fddd topology is reported. Upon removal of guest molecules, the crystal lattice is unaffected, and the resulting permanent porosity can be applied for gas chromatography separation of various organic molecules. Furthermore, remarkable tunable photoluminescence and direct white emission dependent on excitation wavelength, as well as visible light photocatalytic activity, are also observed, creating a new multifunctional material antetype.