[MnIIIMnIV2Mo14O56]17–: A Mixed-Valence Meso-Polyoxometalate Anion Encapsulated by a 64-Nuclearity Silver Cluster

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• 作者：Jian-Yu Wang ; Kuan-Guan Liu ; Zong-Jie Guan ; Zi-Ang Nan ; Yu-Mei Lin ; Quan-Ming Wang
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：July 18, 2016
• 年：2016
• 卷：55
• 期：14
• 页码：6833-6835
• 全文大小：237K
• 年卷期：0
• ISSN：1520-510X

文摘

A 64-nuclearity silver cluster encapsulating a unique POM anion [Mn^IIIMn^IV₂Mo₁₄O₅₆]^17– has been synthesized. The formation of the templating core performs a reassembly process for increasing nuclearities from {MnMo₉} to {Mn₃Mo₁₄}. It represents a rare inorganic meso anion containing mixed-valent Mn that is built up by d-{Mn^IVMo₇} and l-{Mn^IVMo₇} units connecting together through a {Mn^III} fragment.