Orthorhombic Bi2GeO5 Nanobelts: Synthesis, Characterization, and Photocatalytic Properties

详细信息    查看全文

• 作者：Ruigen Chen^† ; ; Jinhong Bi^† ; ; Ling Wu*^‡ ; ; Zhaohui Li^† ; ; Xianzhi Fu*^† ;
• 刊名：Crystal Growth & Design
• 出版年：2009
• 出版时间：April 1, 2009
• 年：2009
• 卷：9
• 期：4
• 页码：1775-1779
• 全文大小：209K
• 年卷期：v.9,no.4(April 1, 2009)
• ISSN：1528-7505

文摘

One-dimensional Bi₂GeO₅ nanobelts were first directly prepared by a surfactant-templated hydrothermal process. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and UV−vis diffuse reflectance spectroscopy were used to characterize the obtained samples. By use of cetyltrimethyl ammonium bromide as the structure-directing template, Bi₂GeO₅ nanobelts with widths of about 70−180 nm were obtained. The mechanisms related to the morphology control of Bi₂GeO₅ are proposed and discussed. The UV−vis absorption spectra show that the as-prepared nanomaterials have a strong absorption edge in UV light and that their band gaps are somewhat relevant to the size and morphology. As a novel photocatalyst, the prepared Bi₂GeO₅ samples exhibit relatively high photocatalytic activity for the decomposition of azo dye methyl orange under UV irradiations. The samples obtained under different amounts of cetyltrimethyl ammonium bromide exhibited different photocatalytic performances. The effects of the crystallinity, specific surface area and morphology of the samples on the photocatalytic activities are also discussed.