Double Interpenetration in a Chiral Three-Dimensional Magnet with a (10,3)-a Structure

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• 作者：Thais Grancha ; Marta Mon ; Francesc Lloret ; Jes煤s Ferrando-Soria ; Yves Journaux ; Jorge Pas谩n ; Emilio Pardo
• 刊名：Inorganic Chemistry
• 出版年：2015
• 出版时间：September 21, 2015
• 年：2015
• 卷：54
• 期：18
• 页码：8890-8892
• 全文大小：271K
• ISSN：1520-510X

文摘

A unique chiral three-dimensional magnet with an overall racemic double-interpenetrated (10,3)-a structure of the formula [(S)-(1-PhEt)Me₃N]₄[Mn₄Cu₆(Et₂pma)₁₂](DMSO)₃]路3DMSO路5H₂O (1; Et₂pma = N-2,6-diethylphenyloxamate) has been synthesized by the self-assembly of a mononuclear copper(II) complex acting as a metalloligand toward Mn^II ions in the presence of a chiral cationic auxiliary, constituting the first oxamato-based chiral coordination polymer exhibiting long-range magnetic ordering.