Unfolding of Isotactic Polypropylene under Uniaxial Stretching

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• 作者：Jia Kang ; Shichen Yuan ; You-lee Hong ; Wei Chen ; Akihiro Kamimura ; Akihiro Otsubo ; Toshikazu Miyoshi
• 刊名：ACS Macro Letters
• 出版年：2016
• 出版时间：January 19, 2016
• 年：2016
• 卷：5
• 期：1
• 页码：65-68
• 全文大小：297K
• ISSN：2161-1653

文摘

Despite numerous investigations on polymer processing, understanding the deformation mechanisms of semicrystalline polymer under uniaxial stretching is still challenging. In this work, ¹³C–¹³C Double Quantum (DQ) NMR was applied to trace the structural evolution of ¹³C-labeled isotactic polypropylene (iPP) chains inside the crystallites stretched to an engineering strain (e) of 21 at 100 °C. DQ NMR based on spatial proximity of ¹³C labeled nuclei proved conformational changes from the folded chains to the locally extended chains induced by stretching. By combining experimental findings with literature results on molecular dynamics, it was concluded that transportation of the crystalline chains plays a critical role to achieve large deformability of iPP.