A Novel Asymmetric Hydroarsination Reaction Promoted by a Chiral Organopalladium Complex

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• 作者：Maricar L. Bungabong ; Kien Wee Tan ; Yongxin Li ; Selvasothi V. Selvaratnam ; Krishna G. Dongol ; Pak-Hing Leung
• 刊名：Inorganic Chemistry
• 出版年：2007
• 出版时间：May 28, 2007
• 年：2007
• 卷：46
• 期：11
• 页码：4733 - 4736
• 全文大小：80K
• 年卷期：v.46,no.11(May 28, 2007)
• ISSN：1520-510X

文摘

The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di--chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reactionpromoter.