Core/Shell Structured TiO2/CdS Electrode to Enhance the Light Stability of Perovskite Solar Cells

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• 作者：Insung Hwang ; Minki Baek ; Kijung Yong
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2015
• 出版时间：December 23, 2015
• 年：2015
• 卷：7
• 期：50
• 页码：27863-27870
• 全文大小：534K
• ISSN：1944-8252

文摘

In this work, enhanced light stability of perovskite solar cell (PSC) achieved by the introduction of a core/shell-structured CdS/TiO₂ electrode and the related mechanism are reported. By a simple solution-based process (SILAR), a uniform CdS shell was coated onto the surface of a TiO₂ layer, suppressing the activation of intrinsic trap sites originating from the oxygen vacancies of the TiO₂ layer. As a result, the proposed CdS-PSC exhibited highly improved light stability, maintaining nearly 80% of the initial efficiency after 12 h of full sunlight illumination. From the X-ray diffraction analyses, it is suggested that the degradation of the efficiency of PSC during illumination occurs regardless of the decomposition of the perovskite absorber. Considering the light-soaking profiles of the encapsulated cells and the OCVD characteristics, it is likely that the CdS shell had efficiently suppressed the undesirable electron kinetics, such as trapping at the surface defects of the TiO₂ and preventing the resultant charge losses by recombination. This study suggests that further complementary research on various effective methods for passivation of the TiO₂ layer would be highly meaningful, leading to insight into the fabrication of PSCs stable to UV-light for a long time.