Intrinsic Yellow Light Phosphor: An Organic-Inorganic Hybrid Gallium Oxalatophosphate with Hexameric Octahedral Ga6(OH)4O26 Cluster

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• 作者：Ya-Ching Yang ; Sue-Lein Wang
• 刊名：Journal of the American Chemical Society
• 出版年：2008
• 出版时间：January 30, 2008
• 年：2008
• 卷：130
• 期：4
• 页码：1146 - 1147
• 全文大小：165K
• 年卷期：v.130,no.4(January 30, 2008)
• ISSN：1520-5126

文摘

An unprecedented intrinsic yellow phosphor with high PL quantum efficiency and a unique MOF-like organic-inorganic hybrid open framework has been synthesized under mild thermal conditions; the structure of NTHU-6 is built from small organic oxalate linkers and large inorganic hexameric octahedral Ga-O clusters; its extraordinary yellow emission was suspected to correlate with defects evoked by disorderliness near large pores with the template presumed to act as a sensitizer.