Densities, Viscosities, and Refractive Indices of Dimethyl Carbonate + 1-Hexanol/1-Octanol Binary Mixtures at Different Temperatures

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• 作者：Mehrdad Moosavi ; Ahmad Motahari ; Amir Vahid ; Vahideh Akbar ; Abbas Ali Rostami ; Abdollah Omrani
• 刊名：Journal of Chemical & Engineering Data
• 出版年：2016
• 出版时间：June 9, 2016
• 年：2016
• 卷：61
• 期：6
• 页码：1981-1991
• 全文大小：610K
• 年卷期：0
• ISSN：1520-5134

文摘

The densities, viscosities, and refractive indices for the binary mixtures of dimethyl carbonate (DMC) + 1-hexanol/1-octanol were measured at atmospheric pressure and temperature of 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, and 323.15 K over the whole concentration range. Different thermodynamic, transport, and optical properties, such as excess molar volume, partial molar volume, thermal expansion coefficient, isothermal coefficient of pressure excess molar enthalpy, activation energy of flow, excess refractive index, and electronic polarizability were obtained from the experimental data. The results were analyzed in terms of specific molecular interactions and mixing behavior between mixture components with taking into considerations the effect of temperature. Moreover, the thermophysical properties were examined with predictive and correlative equations. The quality of the predictions for the studied systems was evaluated by measuring the deviations and drawing the comparison plots.