Aromatic Nitration in Liquid Ag0.51K0.42Na0.07NO3
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- 作者：Mark Mascal ; Lunxiang Yin ; Ross Edwards ; Michael Jarosh
- 刊名：Journal of Organic Chemistry
- 出版年：2008
- 出版时间：August 15, 2008
- 年：2008
- 卷：73
- 期：16
- 页码：6148-6151
- 全文大小：166K
- 年卷期：v.73,no.16(August 15, 2008)
- ISSN：1520-6904
文摘
Aromatic molecules have a strong affinity for silver(I) and dissolve to a limited extent in Ag0.51K0.42Na0.07NO3, a low-melting eutectic mixture of silver, potassium, and sodium nitrates. Aromatic nitration in this inorganic ionic liquid leads to products which arise from nonelectrophilic substitution pathways.