Linear and Nonlinear Optical Spectroscopy of Fluoroalkylated BODIPY Dyes
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- 作者：Dominik K. Kölmel ; Anna Hörner ; Juan A. Castañeda ; Julio A. P. Ferencz ; Angela Bihlmeier ; Martin Nieger ; Stefan Bräse ; Lazaro A. Padilha
- 刊名：Journal of Physical Chemistry C
- 出版年：2016
- 出版时间：March 3, 2016
- 年：2016
- 卷：120
- 期：8
- 页码：4538-4545
- 全文大小：435K
- ISSN：1932-7455
文摘
A series of fluoroalkyl-labeled BODIPY dyes have been synthesized with different substituents on the 2- and 6-positions and investigated in terms of their spectroscopic properties. The dyes were decorated with aryl, alkenyl, and alkynyl substituents, respectively. Those substituents are able to expend the dyes’ delocalized π-electron system to different extents. Detailed linear and nonlinear optical spectroscopy methods as well as quantum-chemical calculations have been employed to verify the influence of those different substituents on the electronic distribution and, ultimately, on the molecules’ optical properties. From the nonlinear optical measurements, we find that the substituents highly influence the excited-state absorption properties, which could be tuned in wavelength by ∼100 nm and in magnitude by over 1 order of magnitude, reaching peak values close to 10–15 cm2 for one of the alkynyl-containing dyes.