文摘
We have synthesized, characterized, and computationally validated the high Brunauer鈥揈mmett鈥揟eller surface area and hydrogen uptake of a new, noncatenating metal鈥搊rganic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.