[Ni(phen)3]2Sb18S29: A Novel Three-Dimensional Framework Thioantimonate(III) Templated by [Ni(phen)3] Complexes
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- 作者：Ke-Zhao Du ; Mei-Ling Feng ; Long-Hua Li ; Bing Hu ; Zu-Ju Ma ; Peng Wang ; Jian-Rong Li ; Yu-Long Wang ; Guo-Dong Zou ; Xiao-Ying Huang
- 刊名：Inorganic Chemistry
- 出版年：2012
- 出版时间：April 2, 2012
- 年：2012
- 卷：51
- 期：7
- 页码：3926-3928
- 全文大小：217K
- 年卷期：v.51,no.7(April 2, 2012)
- ISSN：1520-510X
文摘
A novel thioantimonate(III), namely, [Ni(phen)3]2Sb18S29 (1; phen = 1,10-phenanthroline), has been solvothermally synthesized. Its structure features a three-dimensional framework with the largest channels in thioantimonates. The chiral [Ni(phen)3]2+ cations and the Sb:S ratio (1:1.611) in 1 are unique among those in the reported thioantimonates. The thermal stability, optical properties, and electric conductivity as well as the theoretical band structure and density of state of 1 have also been studied.