Top-Seeded Solution Crystal Growth, Morphology, Optical and Thermal Properties of Ba3(ZnB5O10)PO4

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• 作者：Hongwei Yu ; Jacqueline Cantwell ; Hongping Wu ; Weiguo Zhang ; Kenneth R. Poeppelmeier ; P. Shiv Halasyamani
• 刊名：Crystal Growth & Design
• 出版年：2016
• 出版时间：July 6, 2016
• 年：2016
• 卷：16
• 期：7
• 页码：3976-3982
• 全文大小：480K
• 年卷期：0
• ISSN：1528-7505

文摘

Ba₃(ZnB₅O₁₀)PO₄ (BZBP) single crystals were grown successfully by a top-seeded solution growth method. High-resolution X-ray diffraction rocking curve measurements reveal a full width at half-maximum of 34.56″ of a BZBP single crystal grown from a [101]-oriented seed. The refractive indices from the UV to the near infrared region were measured, and revealed a birefringence of 0.04179–0.03059 in the wavelength range of 253.6–2325.4 nm. In addition the type-I and type-II phase-matching range for second and third harmonic generation were calculated based on the fitted Sellmeier equations. In order to further evaluate the potential application of Ba₃(ZnB₅O₁₀)PO₄, the thermal properties including specific heat, thermal diffusivity, and thermal conductivity were also measured along different crystallographic axes.