Heteroatom Role in Polymeric Dioxyselenophene/Dioxythiophene Systems for Color and Redox Control

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• 作者：James F. Ponder Jr. ; Sandra L. Pittelli ; John R. Reynolds
• 刊名：ACS Macro Letters
• 出版年：2016
• 出版时间：June 21, 2016
• 年：2016
• 卷：5
• 期：6
• 页码：714-717
• 全文大小：276K
• 年卷期：0
• ISSN：2161-1653

文摘

The first example of a solution processable dioxythiophene-alt-dioxyselenophene polymer, ProDOT-EDOS, prepared via direct (hetero)arylation polymerization is reported and its optical and electrochemical properties are compared to the all thiophene analog, ProDOT-EDOT, and other relevant dioxythiophene polymers. By substituting the sulfur atom for a selenium atom on one of the monomers in the repeat unit a significant red-shift of both the neutral (41 nm, 132 meV) and polaronic (106 nm, 126 meV) absorbances results, as well as a 160 mV reduction in the onset of oxidation compared to ProDOT-EDOT. Spray-cast films of the polymer electrochemically switch from a vibrant blue charge neutral state to a color neutral and highly transmissive oxidized state.