Visible-Light-Driven Photocatalytic Initiation of Radical Thiol鈥揈ne Reactions Using Bismuth Oxide
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- 作者：Olugbeminiyi O. Fadeyi ; James J. Mousseau ; Yiqing Feng ; Christophe Allais ; Philippe Nuhant ; Ming Z. Chen ; Betsy Pierce ; Ralph Robinson
- 刊名：Organic Letters
- 出版年：2015
- 出版时间：December 4, 2015
- 年：2015
- 卷：17
- 期：23
- 页码：5756-5759
- 全文大小：355K
- ISSN：1523-7052
文摘
A nontoxic and inexpensive photocatalytic initiation of anti-Markovnikov hydrothiolation of olefins using visible light is reported. This method is characterized by low catalyst loading, thereby enabling a mild and selective method for radical initiation in thiol鈥揺ne reactions between a wide scope of olefins and thiols.