Presynthesized and In-Situ Generated Tetrazolate Ligand in the Design of Chiral Cadmium Coordination Polymer

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• 作者：Che-Chi Chang ; Yun-Chieh Huang ; Sheng-Ming Huang ; Jing-Yun Wu ; Yen-Hsiang Liu ; Kuang-Lieh Lu
• 刊名：Crystal Growth & Design
• 出版年：2012
• 出版时间：August 1, 2012
• 年：2012
• 卷：12
• 期：8
• 页码：3825-3828
• 全文大小：253K
• 年卷期：v.12,no.8(August 1, 2012)
• ISSN：1528-7505

文摘

In contrast to the in-situ generated 5-(4-pyridyl)tetrazolate (4-ptz) ligand, the use of presynthesized 4-ptz led to the formation of a chiral cadmium coordination polymer with a rare 渭₅-bridging mode of the tetrazolate ligand. This type of tuning in the design of chiral coordination polymers is reported for the first time.