Mild, Safe, and Versatile Reagents for (CF2)n Transfer and the Construction of Fluoroalkyl-Containing Rings

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• 作者：Peter T. Kaplan ; Long Xu ; Bo Chen ; Katherine R. McGarry ; Siqi Yu ; Huan Wang ; David A. Vicic
• 刊名：Organometallics
• 出版年：2013
• 出版时间：December 23, 2013
• 年：2013
• 卷：32
• 期：24
• 页码：7552-7558
• 全文大小：402K
• ISSN：1520-6041

文摘

The preparation of new dizinc reagents [(MeCN)₂Zn((CF₂)_n)₂Zn(MeCN)₂] (n = 3, 4, and 6) is reported. We show that the C4 reagent can readily transmetalate nickel to form a mononuclear perfluoronickelacycle. We also demonstrate that the reagents can be used to prepare novel fluoroorganics containing either perfluoroalkyl ring systems or perfluoroalkyl linked arenes under relatively mild conditions.