Novel Means of Controlling the Solid-State Circular Dichroism Property in a Supramolecular Organic Fluorophore Comprising 4-[2-(Methylphenyl)ethynyl]benzoic Acid by Varying the Position of the Methyl
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- 作者：Noriaki Nishiguchi ; Takafumi Kinuta ; Tomohiro Sato ; Yoko Nakano ; Takunori Harada ; Nobuo Tajima ; Michiya Fujiki ; Reiko Kuroda ; Yoshio Matsubara ; Yoshitane Imai
- 刊名：Crystal Growth & Design
- 出版年：2012
- 出版时间：April 4, 2012
- 年：2012
- 卷：12
- 期：4
- 页码：1859-1864
- 全文大小：348K
- 年卷期：v.12,no.4(April 4, 2012)
- ISSN：1528-7505
文摘
The solid-state circular dichroism (CD) of a 4-[2-(methylphenyl)ethynyl]benzoic acid/amine supramolecular organic fluorophore can be controlled by changing the position of the methyl substituent of the methylphenylethynyl unit on the achiral 4-[2-(methylphenyl)ethynyl]benzoic acid component molecule, instead of changing the chirality of the chiral amine component molecule.