Enantiomerically Pure Chiral {CuII32}-Based 2D-Layered Frameworks: From the Asymmetric Octacopper(II) Subcomponents to 3D Hierarchical Supramolecular Structures

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• 作者：Wei Meng ; Feng Xu ; Weijian Xu
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：March 21, 2016
• 年：2016
• 卷：55
• 期：6
• 页码：2673-2675
• 全文大小：304K
• ISSN：1520-510X

文摘

Two new chiral copper(II) coordination polymers comprising octacopper(II) subcomponents were synthesized through investigation of the interplay among tartrate ligands, guanidinium cations, and metals. Our analysis confirms that these compounds are enantiomers exhibiting 3D hierarchical supramolecular structures that are constituted by 2D sublayers and sustained by noncovalent bonding interactions.