We reported herein a smart material (BCLC-FM) with tunable emission by combining a fluorescent molecule (FM) with a bent-core liquid crystal (BCLC). The photoluminescence of BCLC-FM could be modulated in two distinct switching ways by changing the transmittance under different electric fields. The two distinct operating modes are interchangeable and thermo-erasable, which may provide a novel designing strategy to realize the multiswitching modes of photoluminescence of organic compounds.