2-Fold Interpenetrating Bifunctional Cd-Metal–Organic Frameworks: Highly Selective Adsorption for CO2 and Sensitive Luminescent Sensing of Nitro Aromatic 2,4,6-Trinitrophenol

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• 作者：Xu-Jia Hong ; Qin Wei ; Yue-Peng CaiSheng-Run Zheng ; Ying Yu ; Yan-Zhong Fan ; Xian-Yan Xu ; Li-Ping Si
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2017
• 出版时间：February 8, 2017
• 年：2017
• 卷：9
• 期：5
• 页码：4701-4708
• 全文大小：522K
• ISSN：1944-8252

文摘

A robust primitive diamond-type topology 3-D metal–organic framework (MOF) of {[Cd<sub>4sub>(hbhdpy)<sub>2sub>(bdc)<sub>3sub>(DMA)<sub>2sub>]·(H<sub>2sub>O)<sub>4sub>}<sub>nsub> (1, DMA = N,N-dimethylacetamide) was constructed from the planar secondary building units of the dinuclear cadmium clusters, Cd<sub>2sub>(μ<sub>2sub>-O)<sub>2sub>, and two linear organic linkers of the new multidentate Schiff base of 4-(2-hydroxy-3-methoxy-benzyli-denehydrazino-carbonyl)-N-pyridin-4-yl-benzamide (Hhbhdpy) through the solvothermal reaction. 1 presents a 2-fold interpenetrating network along with confined narrow channels and rich acylamide groups as well as potential metal open sites for excellent selective CO<sub>2sub> uptake over CH<sub>4sub>/N<sub>2sub> and high luminescent response for 2,4,6-trinitrophenol (TNP) in DMA solution under ambient conditions. With 2-amino-1,4-dicarboxy-benzene (H<sub>2sub>bdc-NH<sub>2sub>) replacing H<sub>2sub>bdc, an amine-functionalized MOF of {[Cd<sub>4sub>(hbhdpy)<sub>2sub>(bdc-NH<sub>2sub>)<sub>3sub> (DMA)<sub>2sub>]·(H<sub>2sub>O)<sub>4sub>}<sub>nsub> (1-NH<sub>2sub>) as an isomorphism of 1, was synthesized under the same reaction conditions. Compared with 1, the corresponding bifunctional features of 1-NH<sub>2sub> is more obvious. To the best of our knowledge, it is the first reported interpenetrating Cd-MOFs with highly sensitive luminescence response for TNP molecules combined with excellent selectivity for CO<sub>2sub>/N<sub>2sub> and CO<sub>2sub>/CH<sub>4sub>.