A Base-Stabilized Silylene with a Tricoordinate Silicon Atom as a Ligand for a Metal Complex
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- 作者：Wei Yang ; Hao Fu ; Haijun Wang ; Mingqing Chen ; Yuqiang Ding ; Herbert W. Roesky ; Anukul Jana
- 刊名：Inorganic Chemistry
- 出版年：2009
- 出版时间：June 15, 2009
- 年：2009
- 卷：48
- 期：12
- 页码：5058-5060
- 全文大小：634K
- 年卷期：v.48,no.12(June 15, 2009)
- ISSN：1520-510X
文摘
Treatment of base stabilized silylene [PhC(NtBu)2]SiOtBu (1) with a tricoordinate silicon atom and diiron nonacarbonyl [Fe2(CO)9] in tetrahydrofuran led to the formation of {[PhC(NtBu)2]SiOtBu}Fe(CO)4 (2), the first stable metal complex derived from a base-stabilized tricoordinate silylene ligand. The solid-state structure and bonding situation of 2 were investigated with single-crystal X-ray diffraction and quantum chemical calculations.