Flux Crystal Growth and the Electronic Structure of BaFe12O19 Hexaferrite

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• 作者：V. V. Atuchin ; D. A. Vinnik ; T. A. Gavrilova ; S. A. Gudkova ; L. I. Isaenko ; Xingxing Jiang ; L. D. Pokrovsky ; I. P. Prosvirin ; L. S. Mashkovtseva ; Zheshuai Lin
• 刊名：Journal of Physical Chemistry C
• 出版年：2016
• 出版时间：March 10, 2016
• 年：2016
• 卷：120
• 期：9
• 页码：5114-5123
• 全文大小：615K
• ISSN：1932-7455

文摘

The barium hexaferrite, BaFe₁₂O₁₉, microcrystals were obtained by the flux crystal growth method and were characterized by XRD, SEM, and TEM methods. XPS measurements were carried out on a powder sample. The binding energy differences between the O 1s and cation core levels, Δ_Ba = BE(O 1s) – BE(Ba 3d_5/2) and Δ_Fe = BE(O 1s) – BE(Fe 2p_3/2), were used to characterize the valence electron transfer on the formation of Ba–O and Fe–O bonds. The chemical bonding effects were considered on the basis of our XPS results measured for BaFe₁₂O₁₉ and the earlier published structural and XPS data for other Ba- or Fe-containing oxide compounds. The band structure of BaFe₁₂O₁₉ was calculated by spin-polarized DFT methods and compared to the valence band spectrum measured by the XPS method.