Syntheses of Novel Chiral Sulfinamido Ligands and Their Applications in Diethylzinc Additions to Aldehydes

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• 作者：Zhiyan Huang ; Hongshan Lai ; Yong Qin
• 刊名：Journal of Organic Chemistry
• 出版年：2007
• 出版时间：February 16, 2007
• 年：2007
• 卷：72
• 期：4
• 页码：1373 - 1378
• 全文大小：124K
• 年卷期：v.72,no.4(February 16, 2007)
• ISSN：1520-6904

文摘

A novel class of sulfinamido alcohol ligands 1-6 was synthesized from (S)-tert-butanesulfinamide. Theseligands showed excellent catalytic activities and enantiomeric selectivities in asymmetric additions ofdiethylzinc to aromatic aldehydes.