Functionalized polynorbornenes with organosilicon groups in the side chains. Synthesis and photophysical properties

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• 作者：Е. О. Platonova ; Т. А. Kovylina ; Е. V. Baranov…
• 关键词：silicon ; containing carbon ; chain polymers ; norbornene monomers ; metathesis polymerization ; photophysical properties
• 刊名：Russian Journal of General Chemistry
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：86
• 期：1
• 页码：116-124
• 全文大小：540 KB
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• 作者单位：Е. О. Platonova (1)
  Т. А. Kovylina (1)
  Е. V. Baranov (1) (2)
  А. V. Arapova (1)
  L. N. Bochkarev (1) (2)
  
  1. G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia
  2. N.I. Lobachevskii Nizhny Novgorod State University, pr. Gagarina 23, Nizhny Novgorod, 603950, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3350

文摘

Using the method of metathesis polymerization carbon-chain homopolymers containing triрhenylsilyl, tritolylsilyl and trithienylsilyl groups in the side chains, as well as their copolymers with additional carbazole-containing units have been synthesized. Photophysical properties of the obtained compounds were investigated. All polymer products show an intense photoluminescence in the blue region of the spectrum. The largest quantum yield (61.4%) was shown by the copolymer with triphenylsilyl and carbazole side groups.