Synthesis of ferrocene- and azobenzene-based compounds for anion recognition

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• 作者：Xiao-ting Zhai ; Hao-jie Yu ; Li Wang ; Zheng Deng…
• 关键词：Ferrocene ; Azobenzene ; Hydrogen bonding ; High density information storage ; Anion recognition ; 二茂铁
偶氮苯 光电响应 ; 离子识别 ; O69
• 刊名：Journal of Zhejiang University - Science A
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：17
• 期：2
• 页码：144-154
• 全文大小：3,123 KB
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• 作者单位：Xiao-ting Zhai (1)
  Hao-jie Yu (1)
  Li Wang (1)
  Zheng Deng (1)
  Zain-ul Abdin (1)
  Yong-sheng Chen (1)
  
  1. The State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China
  
• 刊物类别：Engineering
• 刊物主题：Physics
  Mechanics, Fluids and Thermodynamics
  Chinese Library of Science
  
• 出版者：Zhejiang University Press, co-published with Springer
• ISSN：1862-1775

文摘

A series of ferrocene- and azobenzene-based compounds with acyl amine groups attached were designed and synthesized to explore their potential application in anion recognition. Their electro- and photo-properties, and the effect of nitro and amine substituents of the benzene ring on anion recognition were studied by UV-vis absorption spectroscopy (UV) and cyclic voltammetry (CV). The results showed that a nitro group substituent has a positive effect on the binding affinity and sensitivity, which might be due to the strong hydrogen bonding interaction between the receptor and the guest, while an amino group substituent has a negative effect on the sensitivity. Furthermore, the shift in the UV-vis absorption spectra was observed as a color change, which can be used for the naked-eye detection of F− and H₂PO ₄ − . Keywords Ferrocene Azobenzene Hydrogen bonding High density information storage Anion recognition