Interface-level thermodynamic stability diagram for in situ internal oxidation of Ag(SnO2)p composites
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  • 作者:Canhui Xu (1) (2)
    Yong Jiang (2) (3)
    Danqing Yi (2) (3)
    Haibin Zhang (1)
    Shuming Peng (1)
    Jianhua Liang (1)

    1. Institute of Nuclear Physics and Chemistry
    ; The Chinese Academy of Engineering Physics ; Mianyang ; 621900 ; China
    2. School of Materials Science and Engineering
    ; Central South University ; Changsha ; 410083 ; China
    3. The Key Lab for Nonferrous Materials of the Ministry of Education
    ; Central South University ; Changsha ; 410083 ; China
  • 刊名:Journal of Materials Science
  • 出版年:2015
  • 出版时间:February 2015
  • 年:2015
  • 卷:50
  • 期:4
  • 页码:1646-1654
  • 全文大小:2,183 KB
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  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Materials Science
    Characterization and Evaluation Materials
    Polymer Sciences
    Continuum Mechanics and Mechanics of Materials
    Crystallography
    Mechanics
  • 出版者:Springer Netherlands
  • ISSN:1573-4803
文摘
We present a combined experimental and theoretical study on interfacial structure and thermodynamics in internally oxidized Ag(SnO2)p composites. The orientation relation between in situ formed SnO2 particles and the silver matrix was characterized using high-resolution transmission electron microscopy techniques. First-principles energetic calculations were then performed to predict the equilibrium interface structures and corresponding adhesion properties as functions of temperature and oxygen partial pressure. All results were combined to construct the interface-level thermodynamic stability diagram, for guiding the optimal design of internal oxidation parameters.

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