K3[Fe(CN)6].3H2O supported on silica gel: An efficient and selective reagent for the cleavage of oximes to their corresponding carbonyl compounds in aqueous medi
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- 作者：ABBAS AMINI MANESH ; BEHZAD SHIRMARDI SHAGHASEMI
- 关键词：K3[Fe(CN)6].3H2O ; Silica gel ; oxime ; aldehyde ; ketone
- 刊名：Journal of Chemical Sciences
- 出版年：2015
- 出版时间：March 2015
- 年：2015
- 卷：127
- 期：3
- 页码：493-497
- 全文大小：989 KB
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BEHZAD SHIRMARDI SHAGHASEMI (1)
1. Department of Chemistry, Payame Noor University, 19395-4697, Tehran, I. R. of IRAN - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Chemistry - 出版者：Springer India
- ISSN：0973-7103
文摘
K3[Fe(CN)6].3H2O supported on silica gel, a new oxidant, for efficient, simple and selective cleavage of ketoximes and aldoximes to their corresponding carbonyl compounds in aqueous medium is described. Further oxidation of aldehydes to carboxylic acid and formation of by-products were not observed. α?em class="EmphasisTypeItalic">β unsaturated oxime was deoximated smoothly without oxidation of the double bond.