Neodymium(III) removal by functionalized magnetic nanoparticles

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• 作者：Abdelkader Miraoui ; Mohamed A. Didi…
• 关键词：Neodymium ; Polyethylenimine ; Maghemite ; Ferrofluid
• 刊名：Journal of Radioanalytical and Nuclear Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：307
• 期：2
• 页码：963-971
• 全文大小：944 KB
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• 作者单位：Abdelkader Miraoui (1)
  Mohamed A. Didi (1)
  Didier Villemin (2)
  
  1. Laboratory of Separation and Purification Technologies, Department of Chemistry, Faculty of Sciences, Tlemcen University, Box 119, 13000, Tlemcen, Algeria
  2. Ecole Nationale Supérieure des Ingénieurs de CAEN & Centre de Recherche, Université de Caen- Basse Normandie, LCMT, UMR CNRS 6507, Labex EMC3, Labex SynOrg, 14050, Caen, France
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Nuclear Chemistry
  Physical Chemistry
  Nuclear Physics, Heavy Ions and Hadrons
  Diagnostic Radiology
  Inorganic Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1588-2780

文摘

In this paper, neodymium removed by liquid-solid extraction is made by magnetic nanoparticles functionalized by the poly(aminoethylene N-methyl 1-formic acid, 1-phosphonic acid) (PAEMFP), with two different sizes. For a quantity of 0.01 g of magnetic particles some parameters were studied. Optimal extraction yield was achieved in a initial pH equal at 7.0 for fine particles and pH 6.0 for the large particles. The experimental capacity obtained was 25 mg g−1 for larges particles and 23 mg g−1 for fines particles. The quantitative elution study of neodymium(III) can be realized with acetic acid 0.5 mol L−1 after 120 min of shaking for two sizes. Keywords Neodymium Polyethylenimine Maghemite Ferrofluid