M?hnite, (NH4)K2Na(SO4)2, a new guano mineral from Pabellón de Pica, Chile
详细信息 查看全文
- 作者：Nikita V. Chukanov ; Sergey M. Aksenov ; Ramiza K. Rastsvetaeva…
- 刊名：Mineralogy and Petrology
- 出版年：2015
- 出版时间：October 2015
- 年：2015
- 卷：109
- 期：5
- 页码：643-648
- 全文大小：661 KB
- 参考文献：Appleton JD, Nothold AJG (2002) Local phosphate resources for sustainable development of Central and South America. Economic Minerals and Geochemical Baseline Programme Report CR/02/122/N. British Geological Survey, Nottingham
Bojar H-P, Walter F (2012) Joanneumite, IMA 2012-01. CNMNC Newsletter No. 13, June 2012, 814. Mineral Mag 76:807-17CrossRef
Bojar H-P, Walter F, Baumgartner J, F?rber G (2010) Ammineite, CuCl2(NH3)2, a new species containing an ammine complex: mineral data and crystal structure. Can Mineral 48:1359-371CrossRef
Chukanov NV (2014) Infrared spectra of mineral species: extended library. Springer-Verlag GmbH, DordrechtCrossRef
Chukanov NV, Britvin SN, M?hn G, Pekov IV, Zubkova NV, Nestola F, Kasatkin AV, Dini M (2015a) Shilovite, natural copper(II) tetrammine nitrate, a new mineral species. Mineral Magaz
Chukanov NV, Zubkova NV, M?hn G, Pekov IV, Zadov AE, Pushcharovsky DY (2015b) Chanabayaite, Cu2(N3C2H2)2Cl(NH3, Cl, H2O,?4, a new mineral species containing triazolate anion. Zapiski Ross Mineral Obshch 144:36-7 (in Russian)
Chukanov NV, Aksenov SM, Rastsvetaeva RK, Lyssenko KA, Belakovskiy DI, F?rber G, M?hn G, Van KV (2015c) Antipinite, KNa3Cu2(C2O4)4, a new mineral species from a guano deposit at Pabellón de Pica, Chile. Mineral Mag
Demartin F, Castellano C, Campostrini I (2014) Therasiaite, (NH4)3KNa2Fe2+Fe3+(SO4)3Cl5, a new sulfate chloride from La Fossa Crater, Vulcano, Aeolian islands, Italy. Mineral Mag 78:203-13CrossRef
Egorov-Tismenko YK, Sokolova EV, Smirnova NL, Yamnova NA (1984) The crystal chemistry of the glaserite-type structures. Mineralogicheskii Zhurnal 6:3- (in Russian)
Ericksen GE (1981) Geology and origin of the Chilean nitrate deposits. Geological Survey Professional Paper 1188. United States Government Printing Office, Washington
Feklichev VG (1989) Diagnostic constants of minerals. Nedra, Moscow (in Russian)
Frondel C (1950) Notes on arcanite, ammonian aphthitalite and oxammite. Am Mineral 35:596-98
Lazoryak BI (1996) Design of inorganic compounds with tetrahedral anions. Russ Chem Rev 65:287-05CrossRef
Mandarino JA (1981) The Gladstone-Dale relationship. Part IV. The compatibility concept and its application. Can Mineral 14:498-02
Moore PB (1973) Bracelets and pinwheels: a topological-geometrical approach to the calcium orthosilicate and alkali sulfate structures. Am Mineral 58:32-2
Moore PB (1981) Complex crystal structures related to glaserite, K3Na(SO4)2: evidence for very dense packings among oxysalts. Bull Soc Fran? Minéral Cristallogr 104:536-47
Nakamoto K (2008) Infrared and raman spectra of inorganic and coordination compounds, theory and applications in inorganic chemistry. Wiley, New YorkCrossRef
Nakamoto K (2009) Infrared and raman spectra of inorganic and coordination compounds, Part B, applications in coordination, organometallic, and bioinorganic chemistry. Wiley, Hoboken
Nikolova R, Kostov-Kytin V (2013) Crystal chemistry of “glaserite-type compounds. Bulg Chem Communs 45:418-26
Okada K, Ossaka J (1980) Structures of potassium sodium sulphate and tripotassium sodium disulphate. Acta Crystallogr B36:919-21CrossRef
Palache C, Berman H, Frondel C (1951) Dana’s system of mineralogy, seventh edition. II:400-03
Pankhurst RJ, Herve F (2007) Introduction and overview. In: Moreno T, Gibbons W (eds): The geology of Chile. Geol Soc London, 414 pp
Petricek V, Dusek M, Palatinus L (2006) Jana2006. Structure determination software programs. Institute of Physics, Prague - 作者单位：Nikita V. Chukanov (1)
Sergey M. Aksenov (2) (3)
Ramiza K. Rastsvetaeva (3)
Igor V. Pekov (4)
Dmitry I. Belakovskiy (5)
Sergey N. Britvin (2)
1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region, 142432, Russia
2. Department of Crystallography, St Petersburg State University, University Embankment 7/9, St Petersburg, 199034, Russia
3. Institute of Crystallography, Russian Academy of Sciences, Leninsky Prospekt 59, Moscow, Russia, 117333
4. Faculty of Geology, Moscow State University, Vorobievy Gory, 119991, Moscow, Russia
5. Fersman Mineralogical Museum of the Russian Academy of Sciences, Leninsky Prospekt 18-2, Moscow, 119071, Russia - 刊物类别：Earth and Environmental Science
- 刊物主题：Earth sciences
Mineralogy
Geochemistry - 出版者：Springer Wien
- ISSN：1438-1168
文摘
The new mineral m?hnite, ideally (NH4)K2Na(SO4)2, the ammonium analogue of aphthitalite, is found in a guano deposit on the Pabellón de Pica mountain, near Chanabaya, Iquique Province, Tarapacá Region, Chile. It is associated with salammoniac, halite, joanneumite, natroxalate, nitratine, chanabayaite, and a clay mineral. M?hnite occurs as random aggregates and clusters of brown imperfect bipyramidal or spindle-shaped crystals. The mineral is brittle, with Mohs-hardness of 3; Dmeas is 2.4(1) g/cm3 and Dcalc is 2.461 g/cm3. The IR spectrum shows the presence of NH4 + cations (the bands at 1431, 3076 and 3240 cm?). M?hnite is almost isotropic, optically neutral; ε-?ω--.505(2). The chemical composition (electron-microprobe data, N determined by gas chromatography of products of ignition, H calculated by stoichiometry, wt%) is: (NH4)2O 7.99, Na2O 9.49, K2O 32.34, SO3 51.32, total 101.14. The empirical formula is (NH4)0.95Na0.95?K2.14S1.99O8. The crystal structure was solved and refined to R--.049 based on 241 unique reflections with I-gt;-σ(I). M?hnite is trigonal, space group P \( \overline{3} \) m1, a--.7402(3) ?, c--.435(1) ?, V--12.16(4) ?3, Z--. The strongest reflections of the powder X-ray diffraction pattern [d, ? (I,%) (hkl)] are: 4.955 (27) (100), 4.122 (37) (101, 011), 3.708 (29) (002), 2.969 (74) (102, 012), 2.861 (100) (110), 2.474 (20) (003), 2.060 (33) (022). The mineral is named in honour of the German amateur mineralogist Gerhard M?hn (born 1959). Editorial handling: A. Beran