A glassy carbon electrode modified with an iron N4-macrocycle and reduced graphene oxide for voltammetric sensing of dissolved oxygen
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- 作者：Saimon M. Silva ; Lucas F. Aguiar ; Rita M. S. Carvalho ; Auro A. Tanaka…
- 关键词：Fe(III) tetra ; (N ; methyl ; 4 ; pyridyl)porphyrin ; Oxygen reduction ; Differential pulse voltammetry ; Scanning electrochemical microscopy ; FTIR ; Microelectrode ; Seawater analysis ; Pond water analysis
- 刊名：Microchimica Acta
- 出版年：2016
- 出版时间：March 2016
- 年：2016
- 卷：183
- 期：3
- 页码：1251-1259
- 全文大小：1,021 KB
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Lucas F. Aguiar (2)
Rita M. S. Carvalho (3)
Auro A. Tanaka (3)
Flavio S. Damos (3)
Rita C. S. Luz (3)
1. School of Chemistry, Australian Centre for NanoMedicine and ARC Centre of Excellence for Bio-Nano Science and Technology, The University of New South Wales, Sydney, NSW, Australia
2. Department of Chemistry, UFVJM, Diamantina, MG, 39100-000, Brazil
3. Department of Chemistry, UFMA, São Luíz, MA, 65080-805, Brazil - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Analytical Chemistry
Inorganic Chemistry
Physical Chemistry
Characterization and Evaluation Materials
Monitoring, Environmental Analysis and Environmental Ecotoxicology - 出版者：Springer Wien
- ISSN：1436-5073
文摘
The authors describe a platform for the electrochemical reduction of oxygen. It is based on the use of a glassy carbon electrode (GCE) that was modified in a single-step microwave assisted reaction with a N4-macrocycle containing iron(III) (FeN4) and with reduced graphene oxide. The FeN4/rGO composite was characterized by cyclic voltammetry, differential pulse voltammetry, and scanning electrochemical microscopy (SECM). Cyclic voltammetry showed the composite to enable efficient reduction of O2 at a very low overpotential (−0.05 V vs. Ag/AgCl). SECM measurements were carried out to map (in the redox competition mode) the activity of a GCE microelectrode modified with FeN4/rGO. Under optimized conditions, the response to dissolved O2 ranges from 0.8 up to 25 mg⋅L‾1, and the limit of detection is 0.2 mg⋅L‾p>1.