Hybrid nanostructured materials with tunable magnetic characteristics
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- 作者：Nubia E. Torres-Martínez (1)
M. A. Garza-Navarro (1) (2)
Domingo García-Gutiérrez (1) (2)
Virgilio A. González-González (1) (2)
Alejandro Torres-Castro (1) (2)
U. Ortiz-Méndez (1) (2) - 关键词：Spinel ; metal ; oxide ; Nanoparticles ; Carboxymethyl ; cellulose ; Cetyltrimethylammonium ; bromide ; Organic template
- 刊名：Journal of Nanoparticle Research
- 出版年：2014
- 出版时间：December 2014
- 年：2014
- 卷：16
- 期：12
- 全文大小：2,003 KB
- 参考文献：1. Anirudhan TS, Gopal SS, Sandeep S (2014) Synthesis and characterization of Montmorillonite/N-(carboxyacyl) Chitosan coated magnetic particle nanocomposites for controlled delivery of paracetamol. Appl Clay Sci 88-9:151-58 CrossRef
2. Berthold J, Olsson RJO, Salmean L (1998) Water sorption to hydroxyl and carboxylic acid groups in carboxymethylcellulose (CMC) studied with NIR-spectroscopy. Cellulose 5:281-98 CrossRef
3. Blanco-Mantecón M, O’Grady K (2006) Interaction and size effects in magnetic nanoparticles. J Magn Magn Mater 296:124-33 CrossRef
4. Bruce IJ, Taylor J, Todd M, Davies M, Borioni E, Sangregorio C, Sen T (2004) Synthesis, characterisation and application of silica-magnetite nanocomposites. J Magn Magn Mater 284:145-60 CrossRef
5. Bueno-Baqués D, Medina-Boudrí A, Matutes-Aquino J (2001) Remanence properties of co-precipitated cobalt ferrite. J Magn Magn Mater 226:1412-414 CrossRef
6. Calero-DdelC VL, Rinaldi C (2007) Synthesis and magnetic characterization of cobalt-substituted ferrite (CoxFe3?xO4) nanoparticles. J Magn Magn Mater 314:60-7 CrossRef
7. Cao S-W, Zhu Y-J, Ma M-Y, Li L, Zhang L (2008) Hierarchically nanostructured magnetic hollow spheres of Fe3O4 and γ-Fe2O3: preparation and potential application in drug delivery. J Phys Chem C 112:1851-856 CrossRef
8. Chaleawlert-umpon S, Pimpha N (2012) Morphology-controlled magnetite nanoclusters via polyethyleneimine-mediated solvothermal process. Mater Chem Phys 135:1- CrossRef
9. Coey JMD (1971) Noncollinear spin arrangement in ultrafine ferrimagnetic crystallites. Phys Rev Lett 27:1140-142 CrossRef
10. Covaliu CI, Jitaru I, Paraschiv G, Vasile E, Biri? S-?, Diamandescu L, Ionita V, Iovu H (2013) Core-shell hybrid nanomaterials based on CoFe2O4 particles coated with PVP or PEG biopolymers for applications in biomedicine. Powder Technol 237:415-26 CrossRef
11. Garza-Navarro MA, Torres-Castro A, García-Gutiérrez DI, Ortiz-Rivera L, Wang YC, González-González VA (2010) Synthesis of spinel-metal-oxide/biopolymer hybrid nanostructured materials. J Phys Chem C 114:17574-7579 CrossRef
12. Garza-Navarro MA, Reyes-Melo ME, González-González V, Guerrero-Salazar C, Ortiz-Méndez U (2012) Modeling of isochronal complex magnetic susceptibility of polymer–magnetic nanocomposites using fractional calculus. J Appl Polym Sci 123:2154-161 CrossRef
13. Gazeau F, Dubois E, Hennion M, Perzynski R, Raikher YL (1997) Quasi-static neutro scattering on γ-Fe2O3 nanoparticles. Europhys Lett 40:575-80 CrossRef
14. Ibusuki T, Kojima S, Kitakami O, Shimada Y (2001) Magnetic anisotropy and behaviors of Fe nanoparticles. IEEE Trans Magn 37:2223-225 CrossRef
15. Kim D-H, Nikles DE, Brazel CS (2010) Synthesis and characterization of multifunctional chitosan-MnFe2O4 nanoparticles for magnetic hyperthermia and drug delivery. Materials - 作者单位：Nubia E. Torres-Martínez (1)
M. A. Garza-Navarro (1) (2)
Domingo García-Gutiérrez (1) (2)
Virgilio A. González-González (1) (2)
Alejandro Torres-Castro (1) (2)
U. Ortiz-Méndez (1) (2)
1. Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Nuevo León, Av. Universidad s/n, Cd. Universitaria, 66451, San Nicolás de los Garza, Nuevo León, Mexico
2. Centro de Innovación, Investigación y Desarrollo en Ingeniería y Tecnología, Universidad Autónoma de Nuevo León, 66600, Apodaca, Nuevo León, Mexico - ISSN：1572-896X
文摘
We report on the development of hybrid nanostructured materials (HNM) based on spinel-metal-oxide nanoparticles (SMON) stabilized in carboxymethyl-cellulose (CMC)/cetyltrimethyl-ammonium-bromide (CTAB)?templates, with tunable magnetic characteristics. These HNM were synthesized using a one-pot chemical approach to obtain CMC/CTAB templates with controllable size and morphology, where the SMON could be densely arranged. The synthesized HNM were characterized by transmission electron microscopy and its related techniques, such as bright field (BF) and Z-contrast (HAADF-STEM) imaging, and selected area electron diffraction, as well as static magnetic measuring. Experimental evidence suggests that the morphology and size of the CMC/CTAB templates are highly dependent on the weight ratio of CTAB:SMON, as well as the hydration days of the CMC that is used for the synthesis of the HNM. Controlling these parameters allows modifying the density of the SMON arrangement in the CMC/CTAB templates. Moreover, magnetic features such as remanence, coercivity, and blocking/de-blocking processes of the particles-magnetic moments are highly dependent on the interactions among the SMON assembled in the templates. Hence, the magnetic characteristics of HNM can be modulated or tuned by controlling the manner the SMON are arranged within the CMC/CTAB templates.