Gas-Phase Hydroformylation of Propene over Silica-Supported PPh3-Modified Rhodium Catalysts
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- 作者：Taejin Kim (1)
Fuat E. Celik (1)
David G. Hanna (1)
S. Shylesh (1)
Sebastian Werner (1) (2)
Alexis T. Bell (1) - 关键词：Propene ; Hydroformylation ; Butanal ; Heterogeneous ; Rhodium ; Silica ; Supported
- 刊名：Topics in Catalysis
- 出版年：2011
- 出版时间：April 2011
- 年：2011
- 卷：54
- 期：5-7
- 页码：299-307
- 全文大小：694KB
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Fuat E. Celik (1)
David G. Hanna (1)
S. Shylesh (1)
Sebastian Werner (1) (2)
Alexis T. Bell (1)
1. Department of Chemical Engineering, University of California, Berkeley, Berkeley, CA, 94720, USA
2. Friedrich-Alexander Universit盲t Erlangen-N眉rnberg, Lehrstuhl f眉r Chemische Reaktionstechnik, Egerlandstra脽e 3, 91058, Erlangen, Germany - ISSN：1572-9028
文摘
Heterogeneous rhodium catalysts supported on SiO2 were modified with PPh3 for the gas-phase hydroformylation of propene to produce n- and isobutanal. High selectivity to aldehydes was achieved, with no propane or alcohols formed. Investigation of the effects of reaction temperature, reactant partial pressures, total pressure, and PPh3/Rh ratio suggested that the supported catalyst behaved similarly to the homogeneous catalyst. In particular, the supported catalyst showed similar activation energies and partial and total pressure dependences of the reaction rates to those observed in homogeneous, liquid-phase reactions. The first order dependence of the hydroformylation rate on the partial pressures of propene, CO, and H2 individually led to a cubic dependence of butanal formation on total pressure for equimolar reactant mixtures. High regioselectivity with a typical n/i ratio of 14 was achieved.