The effect of temperature on the exciton absorption of copper chloride and copper bromide nanocrystals in potassium-aluminum-borate glass
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  • 作者:A. N. Babkina ; N. V. Nikonorov ; V. A. Tsekhomskii…
  • 关键词:nanocrystals ; copper (I) chloride ; melting ; potassium ; aluminum ; borate glass
  • 刊名:Glass Physics and Chemistry
  • 出版年:2015
  • 出版时间:January 2015
  • 年:2015
  • 卷:41
  • 期:1
  • 页码:81-88
  • 全文大小:421 KB
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    7. Kim, A.A., Nikonorov, N.V., Sidorov, A.I., and Tsekhomsky, V.A., Nonlinear optical response of potassium aluminum borate glasses with nanocrystals of copper halides, / NauchnoTekh. Vestn. S.-Peterb. Gos. Univ. Inf. Tekhnol., Mekh. Opt., 2011, no. 3 (73), pp. 26-8.
    8. Kim, A.A. and Shirshnev, P.S., Nonlinear optical effects in potassium aluminum borate glasses with copper chloride nanoparticles, / NauchnoTekh. Vestn. St.-Peterb. Gos. Univ. Inf. Tekhnol., Mekh. Opt., 2010, no. 3 (67), p. 127.
    9. Golubkov, V.V., Kim, A.A., Nikonorov, N.V., Tsekhomskii, V.A., and Shirshnev, P.S., Precipitation of nanosized crystals of CuBr and CuCl in potassium aluminoborate glasses, / Glass Phys. Chem., 2012, vol. 38, no. 3, pp. 259-68. CrossRef
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  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Ceramics,Glass,Composites,Natural Materials
    Characterization and Evaluation Materials
    Materials Science
    Physical Chemistry
    Russian Library of Science
  • 出版者:MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
  • ISSN:1608-313X
文摘
The absorption spectra of nanosized crystals of copper (I) halides distributed in the potassium-aluminum borate glass system were investigated in the region of the exciton absorption band in the temperature range from 20 to 300°C. The temperature dependences of the exciton absorption band of CuHal (Hal = Cl, Br) nanocrystals, which were obtained upon the heating and cooling of the sample, have a form of hysteresis. The melting (140-40°C) and crystallization (35-05°C) temperatures of copper (I) halide nanocrystals contained in the potassium-aluminum borate glass were determined by the optical spectroscopy method.

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