Polypyrrole-polyaniline/Fe3O4 magnetic nanocomposite for the removal of Pb(II) from aqueous solution
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- 作者：Amirhossein Afshar ; Seyed Abolfazl Seyed Sadjadi…
- 关键词：Polypyrrole ; polyaniline ; Nanocomposite ; Lead ; Heavy Metals ; Fe3O4 ; Kinetic
- 刊名：Korean Journal of Chemical Engineering
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：33
- 期：2
- 页码：669-677
- 全文大小：2,699 KB
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Seyed Abolfazl Seyed Sadjadi (1)
Afsaneh Mollahosseini (1)
Mohammad Reza Eskandarian (1) (2) (3) (4)
1. Faculty of Chemistry, Iran University of Science & Technology, Tehran, Iran
2. Department of Applied Chemistry, Faculty of Chemistry, Semnan University, Semnan, Iran
3. Department of Chemistry, University of Zanjan, Zanjan, Iran
4. Zanjan Zinc Khalessazan Industrial Companies (ZZKICO), Zanjan, Iran - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Industrial Chemistry and Chemical Engineering
Catalysis
Materials Science
Biotechnology - 出版者：Springer New York
- ISSN：1975-7220
文摘
Lead ion which is engaged in aqueous solution has been successfully removed. A novel technique was utilized for the separation and absorption of Pb(II) ions from aqueous solution. Magnetic Fe3O4 coated with newly investigated polypyrrole-polyaniline nanocomposite was used for the removal of extremely noxious Pb(II). Characteristic of the prepared magnetic nanocomposite was done using X-ray diffraction pattern, Field emission scanning electron microscopy (FE-SEM), Fourier transform-infra red spectroscopy (FT-IR) and energy dispersive x-ray spectroscopy (EDX). Up to 100% adsorption was found with 20mg/L Pb(II) aqueous solution in the range of pH=8-10. Adsorption results illustrated that Pb(II) removal efficiency by the nanocomposite increased with an enhance in pH. Adsorption kinetics was best expressed by the pseudo-second-order rate form. Isotherm data fitted well to the Freundlich isotherm model. Upon using HCl and HNO3, 75% PPy-PAn/Fe3O4 nanocomposite, desorption experiment showed that regenerated adsorbent can be reused successfully for two successive adsorption-desorption cycles without appreciable loss of its original capacity. Keywords Polypyrrole-polyaniline Nanocomposite Lead Heavy Metals Fe3O4 Kinetic