Time-Dependent Methane Diffusion Behavior in Coal: Measurement and Modeling

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• 作者：Gaowei Yue ; Zhaofeng Wang ; Ce Xie ; Xu Tang ; Junwei Yuan
• 关键词：Coal ; Gas ; Methane ; Diffusion coefficient ; Time ; dependent
• 刊名：Transport in Porous Media
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：116
• 期：1
• 页码：319-333
• 全文大小：
• 刊物类别：Earth and Environmental Science
• 刊物主题：Geotechnical Engineering & Applied Earth Sciences; Industrial Chemistry/Chemical Engineering; Hydrology/Water Resources; Civil Engineering; Hydrogeology; Classical and Continuum Physics;
• 出版者：Springer Netherlands
• ISSN：1573-1634
• 卷排序：116

文摘

In-depth understanding of how methane diffuses in porous media like coal is critical for enhanced coalbed methane recovery and coal seam methane drainage. However, the classic unipore gas diffusion model can only describe methane diffusion behavior in coal at the early time diffusion stage. Describing the whole methane diffusion behavior in coal has not been reasonably addressed in the coalbed methane field. Considering the large surface-to-volume ratio of coal, the authors proposed a time-dependent gas diffusion model to describe the whole diffusion process. This work first proposed a power–law relationship between diffusion coefficient and time according to previous studies of the time-dependent gas diffusion process in porous media. Then, both the analytical solution and its approximation solution for the time-dependent gas diffusion model were derived. Six methane diffusion tests in crushed coal were conducted to validate the proposed model under different pressures (0.5, 1.5, 2.5 MPa) and temperatures (20 and \(30\,{^{\circ }}\hbox {C}\)). Modeling results show that the time-dependent gas diffusion model is superior to the classic unipore gas diffusion model for describing the whole methane diffusion process in coal. Increasing temperature always accelerates methane diffusion in coal; the higher the temperature the larger the diffusion coefficient.