Complex formation between derivatives of pyridine N-oxides and iron(III) nitrate in aqueous medium

详细信息    查看全文

• 作者：A. V. Ryzhakov ; V. P. Andreev
• 关键词：heteroaromatic N ; oxide ; iron(III) nitrate ; molecular complex ; stability constant ; Benesi–Hildebrand method
• 刊名：Russian Journal of General Chemistry
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：86
• 期：1
• 页码：92-95
• 全文大小：247 KB
• 参考文献：1.Ochiai, E., Aromatic Amine Oxides, Amsterdam: Elsevier, 1967.
  2.Albini, A. and Pietra, S., Heterocyclic N-Oxides. Boca Raton; Ann Arbor; Boston: CRC Press, 1991.
  3.Ryzhakov, A.V. and Rodina, L.L., Heterocycles, 2008, vol. 75, no. 10, p. 2367. DOI: 10.3987/REV-08-630.CrossRef
  4.Ryzhakov, A.V. and Andreev, V.P., Russ. J. Gen. Chem., 2005, vol. 75, no. 1, p. 121. DOI: 10.1007/s11176-005-0182-5.CrossRef
  5.Andreev, V.P., Ryzhakov, A.V., Morozov, A.K., Alexeeva, O.O., and Rodina, L.L., Chem. Heterocycl. Compd., 1995, vol. 31, no. 6, p. 671. DOI: 10.1007/BF01169067.CrossRef
  6.Garvey, R.G., Nelson, J.N., and Ragsdale, R.O., Coord. Chem. Rev., 1968, no. 3, p.375.CrossRef
  7.Linnik, P.N. and Nabivanets, B.I., Formy migratsii metallov v presnykh poverkhnostnykh vodakh (Migration Forms of Metals in Fresh Surface Waters), Leningrad: Gidrometeoizdat, 1986.
  8.Ryzhakov, A.V., Andreev, V.P., and Rodina, L.L., Heterocycles, 2003, vol. 60, no. 2, p. 419. DOI: 10.3987/COM-02-9592.CrossRef
  9.Karayannis, N.M., Pytlewski, L.L., and Mikulski, C.M., Coord. Chem. Rev., 1973, no. 11, p. 93.CrossRef
  10.Sverdlova, O.V., Elektronnye spektry v organicheskoi khimii (Electronic Spectra in Organic Chemistry), Leningrad: Khimiya, 1985, p. 202.
  11.Ripan, R. and Chetianu, I., Neorganicheskaya khimiya (Inorganic Chemistry), Moscow: Mir, 1972, vol. 2, p. 528.
  12.Rodina, L.L. and Ryzhakov, A.V., Heterocycles, 1995, vol. 40, no. 2, p. 1035. DOI: 10.3987/REV-94-SR3.CrossRef
  13.Andreev, V.P. and Ryzhakov, A.V., Chem. Heterocycl. Compd., 1993, vol. 29, no. 12, p. 1435. DOI: 10.1007/BF00531407.CrossRef
  
• 作者单位：A. V. Ryzhakov (1)
  V. P. Andreev (2)
  
  1. Institute of Northern Water Problems, Karelian Research Centre, Russian Academy of Sciences, pr. Aleksandra Nevskogo 50, Petrozavodsk, 185003, Russia
  2. Petrozavodsk State University, Petrozavodsk, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3350

文摘

Donor-acceptor complexes of derivatives of pyridine N-oxides with iron(III) nitrate have been studied. Their stability constants in water and in aqueous acetone have been determined. The complexes stability increases upon heating, at decreasing solvent polarity, and in the presence of the substituents in the N-oxide ring.