Hydrogenation of aromatic nitro compounds on palladium-containing anion-exchange resins

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• 作者：M. G. Abdullaev ; Z. G. Gebekova
• 关键词：synthesis ; hydrogenation ; aromatic amines ; palladium ; containing anion ; exchange resins
• 刊名：Petroleum Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：56
• 期：2
• 页码：146-150
• 全文大小：243 KB
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• 作者单位：M. G. Abdullaev (1)
  Z. G. Gebekova (2)
  
  1. Dagestan State University, ul. Gadzhieva 43a, Makhachkala, Dagestan, 367025, Russia
  2. lagestan State Pedagogical University, ul. Yaragskogo 57, Makhachkala, Dagestan, 367003, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1555-6239

文摘

Hydrogenation of aromatic nitro compounds to the corresponding amines on palladium-containing anion-exchange resins has been studied under mild conditions. It has been found that stericity has a significant effect on the activity and selectivity of the hydrogenation reaction. High efficiency of the palladium-containing anion-exchange resins in the synthesis of aromatic amines has been demonstrated. Halonitrobenzenes undergo intense dehalogenation resulting in a low yield of the corresponding amine.