Sorption, kinetics and thermodynamics studies of atrazine herbicide removal from water using iron nano-composite material

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• 作者：I. Ali ; Z. A. ALOthman ; A. Al-Warthan
• 关键词：Adsorption ; Atrazine ; Gas chromatography–mass spectrometry ; Iron composite nanoparticles ; Isotherms ; Kinetics ; Thermodynamics ; Water treatment
• 刊名：International Journal of Environmental Science and Technology
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：13
• 期：2
• 页码：733-742
• 全文大小：738 KB
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• 作者单位：I. Ali (1)
  Z. A. ALOthman (2)
  A. Al-Warthan (2)
  
  1. Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi, 110025, India
  2. Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Kingdom of Saudi Arabia
  
• 刊物主题：Environment, general; Environmental Science and Engineering; Environmental Chemistry; Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution; Soil Science & Conservation; Ecotoxicology;
• 出版者：Springer Berlin Heidelberg
• ISSN：1735-2630

文摘

Atrazine organic pollutant has been found in several water resources of the world. It is highly toxic and carcinogenic in nature. Atrazine is removed by adsorption on iron composite nanoparticles. The composite nanoparticles were synthesized, analyzed and applied for atrazine uptake from water. Residual atrazine was monitored by gas chromatography–mass spectrometry. The maximum atrazine removal (95 %) was achieved using contact time 30.0 min, concentration 30.0 µg/L, pH 7.0, dose 2.5 g/L and temperature 20.0 °C. The adsorbent was selective for atrazine adsorption. The results obeyed Langmuir, Freundlich, Temkin and Dubinin–Radushkevich isotherms. ΔG° values were −6.05, −6.11 and −6.15 kJ/mol at 20, 25 and 30 °C temperatures, respectively. The value of ΔS° was −2.45 × 10−3 kJ/mol K. It showed decline in entropy of atrazine uptake. The adsorption followed pseudo-second-order kinetics. The adsorption mechanism was liquid film diffusion. The proposed adsorption method is inexpensive, fast and reproducible. It can be used to remove atrazine from any water sample/source.