Recovery of Au(III) ions by Au(III)-imprinted hydrogel

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• 作者：Melike Fırlak ; Soner Çubuk ; Ece Kök Yetimoğlu ; Memet V. Kahraman
• 关键词：ion imprinted hydrogel ; 4 ; acryloylmorpholine ; gold(III) removal ; UV curing
• 刊名：Chemical Papers
• 出版年：2016
• 出版时间：June 2016
• 年：2016
• 卷：70
• 期：6
• 页码：757-768
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering; Biochemistry, general; Medicinal Chemistry; Materials Science, general; Biotechnology;
• 出版者：Springer International Publishing
• ISSN：1336-9075
• 卷排序：70

文摘

A new Au(III)-imprinted hydrogel (Au(III)-Imp) was prepared by the photopolymerisation of 4-acryloylmorpholine (AcM), 2-hydroxyethyl acrylate (HEA), and poly(ethylene glycol) diacrylate (cross-linking monomer, PEG-DA) in the presence of gold ions. In addition, non-imprinted hydrogel (N-Imp) was similarly prepared without Au(III) ions The Au(III)-Imp hydrogel was characterised by several techniques. To achieve the optimal conditions, effect of pH, time, and initial metal ion concentrations were investigated using a batch system. The pre-concentration factor for Au(III) ions was found to be at least 100. The analytical parameters of the method were determined and the method was also successfully applied to computer circuit board scrap samples. The reusability of the Au(III)-Imp hydrogel was also determined.