Effect of B2O3 on Structure and Properties of CaO–MgO–B2O3–Al2O3–SiO2 Glasses

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• 作者：Sanxi Huang ; Sheng Li ; Fengnian Wu…
• 关键词：Aluminoborosilicate ; B2O3 ; Dielectric properties ; Glass thermal stability
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2015
• 出版时间：July 2015
• 年：2015
• 卷：25
• 期：4
• 页码：816-822
• 全文大小：906 KB
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• 作者单位：Sanxi Huang (1)
  Sheng Li (1)
  Fengnian Wu (1)
  Yunlong Yue (1)
  
  1. Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, School of Materials Science and Engineering, University of Jinan, Jinan, 250022, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451

文摘

xB2O3-(1???x) (60SiO2-5Al2O3-5MgO-0CaO) glasses with various x around 5-0?mol% at the step of 5?mol% are prepared by the melting-quenching method at 1,450?°C for 3?h. The IR data indicate that replacing other components by B2O3 levels up the amount of [BO4] tetrahedron and boron-oxygen rings, forcing [AlO4] tetrahedron to drop gradually. The glass transition temperature (Tg), crystallization temperature (Tc) and thermal stability (?T) rise when B2O3 is present in lower concentrations (?0?mol%); accordingly the glass network enhances. However, further increase in concentration of B2O3 (>20?mol%) reduces the Tg, Tc and ?T. We utilize temperature-gradient furnace to measure the G6 glass, while the re-melt sample and crystallized phase are observed from polarizing microscope destroying microstructure. As B2O3 content move up, falls in dielectric constant (εr) and loss (tanδ) can be associated with drop of cations polarizability as well as concentration, along with glass network rigidity ascending.