Synthesis and electrochemical evaluation of La1−x Sr x MnO3 catalysts for zinc-air batteries
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- 作者：Guanghua Li ; Ke Zhang ; Mohammed Adnan Mezaal…
- 关键词：Zinc ; air batteries ; Oxygen reduction ; Oxygen evolution ; Perovskite
- 刊名：Journal of Solid State Electrochemistry
- 出版年：2016
- 出版时间：February 2016
- 年：2016
- 卷：20
- 期：2
- 页码：421-427
- 全文大小：1,384 KB
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Ke Zhang (1)
Mohammed Adnan Mezaal (1)
Lixu Lei (1)
1. School of Chemistry and Chemical Engineering, Southeast University, Nanjing, 211189, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Physical Chemistry
Analytical Chemistry
Industrial Chemistry and Chemical Engineering
Characterization and Evaluation Materials
Condensed Matter
Electronic and Computer Engineering - 出版者：Springer Berlin / Heidelberg
- ISSN：1433-0768
文摘
La1-x Sr x MnO3 (x = 0.1∼0.4) catalysts for primary and rechargeable zinc-air batteries have been successfully synthesized by the citrate method and their electrochemical properties measured. The materials can catalyze both ORR and OER, and the one with ideal composition of La0.8Sr0.2MnO3 catalyst exhibits the highest catalytic activity and durability in alkaline medium. The resulting primary zinc-air cell shows a peak power density of 146 mW cm−2 at 235 mA cm−2. The secondary cell exhibits a charge-discharge voltage gap of 1.0 V at 10 mA cm−2, which is highly stable over many charge-discharge cycles. Keywords Zinc-air batteries Oxygen reduction Oxygen evolution Perovskite